Display MoreAnd yes I will probably sell the Focusrite in a few months and get a Apollo Quad rack in hopes that it will be better quality all the way around.
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I also hate how I have to keep adjusting the volume on the Focusrite to try and get it to be exactly the same volume level as the Kemper, because if the Kemper is a little louder than that's probably playing tricks on my mind making me think its better.
I keep unplugging the headphones out of the Focusrite, putting them in the Kemper, back and forth over and over again every 5 seconds, trying to notice the differences in sound, I still think the Kemper may sound a little more Full and Larger, more exciting, than what I hear on the Focusrite, but I'm not sure yet if that's just my imagination or maybe there's there's a difference in volume levels that's causing deception...
I also run my Kemper via S/PDIF into a Scarlett 6i6. I don't think it's your imagination that the Kemper headphone out sounds better than the Focusrite headphone out. I remember doing some A/Bing similar to what you describe and thinking it didn't sound quite as good using headphones via the Focusrite. could be the headphone pre-s on the focusrite aren't that good, not sure.
Anyway, I also struggled with the Focusrite control software when I was trying to use the focusrite as a mixer in addition to an audio interface. Not worth the struggle in my opinion. Now my set up is much better for my needs and only required adding a small 4-channel mackie mixer and no need to upgrade the Focusrite - it is still used for tracking in my DAW but not for any mixer stuff or audio monitoring. the mackie mixer handles that beautifully and no loss in tone versus using Kemper's direct headphone out.
I described my set up in this post:
Studio Monitors Issue and FRFR Advice