I just did a little experimenting.
The Monitor Output level is indeed dependent on the power amp boost level (Elvis wins the free beer!), and whether or not the power amp is turned on.
The factory default (on my unit at least) for power amp boost is +6 dB. With the power amp ON, turning the boost level up and down affects the Monitor Output accordingly. With the power amp ON and the boost level set to 0 dB, the Monitor Output level is the same as if the power amp is OFF.
My powered stage monitor, running off the Monitor Output, has plenty of juice to rip my head off even with the power amp off.
From a design or end-use point of view, I'm puzzled as to why Kemper linked these two outputs - or, rather, made the Monitor Output level dependent on the power amp boost level and ON/OFF state.
The documentation clearly states that these two signals are linked internally. From the 5.5 Main Manual, page 77:
"The most common purpose of the built-in power amp of the models PowerHead and PowerRack is to drive a guitar cabinet, therefore it is cabled internally to the MONITOR OUTPUT. However, the MONITOR OUTPUT jack carries the exact same signal in parallel, so you can still use the MONITOR OUTPUT as if the power amp wasn't there."
Well, OK.