Andy, I understand what you are trying to do.
However please take it from the ultimate analog-loving guy, until you actually hear the Kemper you cannot quite understand how game-changing it is.
If you profile you amp / cab with the settings you like, it is extremely unlikely that you would want to haul around the actual amp / cab for a gig. The Kemper is really that good. We could argue if it is 100% or 98% but none of this is relevant. I have lifted tube amps and guitar cabs and the weight difference will decide the live setup in favor of the Kemper.
So forget about the effects loop, if you have a friend who has a Kemper, just try it.
Also, @Wheresthedug is correct, all of the heavy lifting (literally in this case) would be only for you, unless you are mic-ing the cab. Otherwise the Kemper "pre-amp + effect" signal is going to the FOH and only you are listening to the magnificent Archon power amp distortion and the cab.
If you only want effects, like others have said, there are way cheaper options.
Side-note : I do have an Archon profile on our Kemper and it is one of our favorites. I love PRS guitars as well (my son plays a semi-hollow custom 22) so I know where you are coming from in terms of that tone!