One problem I can see with using your guitar cab for producing convolution verbs, the sharp transient needed for making those could shred your speakers into confetti.
I know you were joking, but it's a fair consideration. Fortunately the inertia of the cone and whatnot, along with the frequency response of the speaker, would round the edges of the pulse out nicely.
The resulting room IR wouldn't be like one that's captured following the usual starter-pistol / popped-balloon that's fit-for-all-purposes, but rather, one that's tailored to the sorts of room responses one might expect from whichever cabinet was used - perfect for a Kemper Profile captured under the same conditions (amp-and-cab setup).